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Lines 18 to 25 are new. Experiments and theory show that the molar entropy of a gas or solute varies logarithmically with concentration (c): The ideal gas equation (Equation ) can be rearranged to show that the concentration of a gas, which is moles of gas per unit volume, is conveniently measured by its partial pressure (p): Applying this equality to both c andwe find that for a gas, the concentration ratio equals the pressure ratio: Since andwe can simplify the equations for entropies of trading djia and solutes djja their concentrations differ from standard conditions, obtaining Equation : Remember, however, that concentration always must be expressed using the same units as the standard state of the substance: bar for gases and molarity for solutes.

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